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DIGITAL.CSIC
Article . 2010 . Peer-reviewed
Data sources: DIGITAL.CSIC
Journal of The Electrochemical Society
Article . 2006 . Peer-reviewed
Data sources: Crossref
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Comparison by SEM, TEM, and EIS of Hydrothermally Sealed and Cold Sealed Aluminum Anodic Oxides

Authors: López, Víctor; Bartolomé, Mª. J.; Escudero, Esther; Otero, Eduardo; González, J. A.;

Comparison by SEM, TEM, and EIS of Hydrothermally Sealed and Cold Sealed Aluminum Anodic Oxides

Abstract

8 pages.-- PACS: 82.45.Cc; 68.55.Jk; 82.45.Rr; 82.80.Fk; 81.65.-b A comparative study is made of the changes caused to the microstructure of anodic films by traditional hydrothermal sealing (HTS) and cold sealing (CS) processes, using the scanning electron microscopy (SEM) and transmission electron microscopy (TEM) techniques. SEM and TEM make it possible to visualize the different stages of the very complex sealing and aging mechanism of aluminum anodic oxide coatings indirectly determined by other techniques, showing evidence of the hexagonal structure of anodic coatings, plugging of the pore mouth with the formation of acicular pseudobohemite and the intermediate sublayers in HTS. It is also possible to verify, both in the coatings resulting from CS and in those subjected to HTS, the stages of dissolution-precipitation, with prior enlargement of the pore diameter and subsequent plugging of the entire pore length. For its part, electrochemical impedance spectroscopy (EIS) provides precise information on the effects of the aging process of anodic layers and their persistence over years and decades. Peer reviewed

Country
Spain
Keywords

Anodisation, Ageing, Dissolving, Thin films, Scanning electron microscopy, Electrochemical impedance spectroscopy, Transmission electron microscopy

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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