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DIGITAL.CSIC
Article . 2010 . Peer-reviewed
Data sources: DIGITAL.CSIC
The Journal of Chemical Physics
Article . 2010 . Peer-reviewed
Data sources: Crossref
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Long-lasting molecular alignment: Fact or fiction?

Authors: Ortigoso, Juan; Rodríguez, Mirta; Santos, Julio; Karpati, Attila; Szalay, Viktor;

Long-lasting molecular alignment: Fact or fiction?

Abstract

It has been suggested that appropriate periodic sequences of laser pulses can maintain molecular alignment for arbitrarily long times [J. Ortigoso, Phys. Rev. Lett. 93, 073001 (2004)]. These aligned states are found among the cyclic eigenstates of truncated matrix representations of the one-period time propagator U(T,0). However, long time localization of periodic driven systems depends on the nature of the spectrum of their exact propagator; if it is continuous, eigenstates of finite-basis propagators cease to be cyclic, in the long time limit, under the exact time evolution. We show that, for very weak laser intensities, the evolution operator of the system has a point spectrum for most laser frequencies, but for the laser powers needed to create aligned wave packets it is unknown if U(T,0) has a point spectrum or a singular continuous spectrum. For this regime, we obtain error bounds on the exact time evolution of rotational wave packets that allow us to determine that truncated aligned cyclic states do not lose their alignment for millions of rotational periods when they evolve under the action of the exact time propagator.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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