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Recolector de Ciencia Abierta, RECOLECTA
Article . 2005 . Peer-reviewed
License: CC BY
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Recolector de Ciencia Abierta, RECOLECTA
Article . 2005 . Peer-reviewed
License: CC BY
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The isotherm slope. A criterion for studying the adsorption mechanism of benzotriazole on copper in sulphuric acid

Authors: Bastidas, David M.; Gómez, R. R.; Cano Díaz, Emilio;

The isotherm slope. A criterion for studying the adsorption mechanism of benzotriazole on copper in sulphuric acid

Abstract

[ES] En el presente trabajo se estudia la adsorción del benzotriazol (BTA) sobre el cobre en solución de ácido sulfúrico con concentraciones de 0,001, 0,005 y 0,01 M utilizando medidas gravimétricas. La concentración de BTA ensayada varió de 1x10'^ M a 1x10'^ M y la temperatura de 298 K a 328 K. El mecanismo de adsorción se analiza en términos de la aplicabilidad de las isotermas convencionales de Frumkin, Bockris-Swinkels y Kastening- HoUeck, entre otras. La mejor descripción de los resultados se obtuvo utilizando la isoterma de Frumkin. Para analizar la orientación del BTA en el proceso de adsorción sobre el cobre, se calculó la superficie de la molécula de BTA.

[EN] The adsorption of benzotriazole (BTA) on copper surfaces in 0.001, 0.005 and 0.01 M concentrations of sulphuric acid was investigated using gravimetric measurements. BTA was tested in concentrations from 1x10 to 1x10 M at temperatures from 298 to 328 K. The adsorption mechanism is discussed in terms of applicability of the conventional Frumkin, Bockris-Swinkels and Kastening-Holleck isotherms, among others. The best fit was obtained using the Frumkin isotherm model. The projected molecular area of BTA was calculated to elucidate inhibitor orientation in the adsorption process.

9 pages, 7 figures, 2 tables.

Peer reviewed

Keywords

isoterma de adsorción, Isoterma de adsorción, Adsorption isotherms, Sulphuric acid. Benzotriazole, benzotriazol, función objetivo, Benzotriazol, Cobre, Área molecular proyectada, Projected molecular area, Función objetivo, Objective function, área molecular proyectada., ácido sulfúrico, Copper, Acido sulfúrico

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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