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Source apportionment of highly time resolved trace elements during a firework episode from a rural freeway site in Switzerland

Authors: Pragati Rai; Markus Furger; Jay G. Slowik; Francesco Canonaco; Roman Fröhlich; Christoph Hüglin; María Cruz Minguillón; +3 Authors
APC: 1,814.77 EUR

Source apportionment of highly time resolved trace elements during a firework episode from a rural freeway site in Switzerland

Abstract

Abstract. Trace element measurements in PM10 were performed with 1 h time resolution at a rural freeway site during summer 2015 in Switzerland using the Xact multi-metals monitor. On average the Xact 625 elements (without accounting for oxygen and other associated elements) make up about 20 % of the total PM10 mass (14.6 µg m−3). Subsequently, a source apportionment by positive matrix factorization (PMF) implemented via the Source Finder software (SoFi Pro) was applied. Eight different sources were identified (notable elements in brackets) for PM10: fireworks-I (K, S, Ba, Cl), fireworks-II (K), sea salt (Cl), secondary sulfate (S), background dust (Si, Ti), road dust (Ca), traffic-related (Fe) and industrial (Zn, Pb). The major components were secondary sulfate and traffic-related followed by background dust and road dust factors, explaining 21 %, 20 %, 18 % and 16 % of the analysed PM10 elemental mass, respectively, with the factor mass not corrected for oxygen content. Further, there are minor contributions (on the order of a few percent) of sea salt and industrial sources. The regionally influenced secondary sulfate factor experiences negligible resuspension, and concentrations are similar throughout the day. The significant loads of the traffic-related and road dust factors with strong diurnal variations highlight the continuing importance of vehicle-related air pollutants at this site. Enhanced control of PMF using SoFi Pro allowed for a successful apportionment of transient sources such as the two firework factors and sea salt, which remained mixed when analysed by unconstrained PMF.

Keywords

Chemistry, Trace elements, PM10, Physics, QC1-999, QD1-999, Air pollutants

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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