Photophysical Studies and Excited-State Structure of a Blue Phosphorescent Gold−Thallium Complex

descriptionPublicationkeyboard_double_arrow_right Article 21 Mar 2007 English Publisher:American Chemical Society (ACS)Journal:Inorganic Chemistry, volume 46, pages 2,953-2,955 (issn: 0020-1669, eissn: 1520-510X,

Copyright policy )

Authors: Fernández, Eduardo J.; Laguna, Antonio; López-de-Luzuriaga, José M.; Monge, Miguel; Montiel, Manuel; Olmos, M. Elena;

doi: 10.1021/ic062127g

pmid: 17373786

handle: 10261/19296

Photophysical Studies and Excited-State Structure of a Blue Phosphorescent Gold−Thallium Complex

- Summary
- Subjects
- Metrics

Abstract

The dinuclear complex [[Tl(eta6-toluene)][Au(C6Cl5)2]] (1) displays very intense blue phosphorescence and a rigidochromic behavior in the solid state. The photophysical measurements in a glassy solution display an oligomerization process via metal-metal interactions. Density functional theory calculations show a distortion of the aurate-thallium T shape in the lowest triplet excited state, leading to a triplet metal-to-metal charge-transfer state.

Related Organizations

Keywords

Models, Molecular, Luminescent Agents, Models, Chemical, Photochemistry, Organometallic Compounds, Gold, Thallium, Crystallography, X-Ray

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	41
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Top 10%
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Top 10%