Metal−Organic Scandium Framework: Useful Material for Hydrogen Storage and Catalysis

descriptionPublicationkeyboard_double_arrow_right Article 22 Oct 2005 English Publisher:American Chemical Society (ACS)Journal:Chemistry of Materials, volume 17, pages 5,837-5,842 (issn: 0897-4756, eissn: 1520-5002,

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Authors: Perles, Josefina; Iglesias, Marta; Martín-Luengo, María Ángeles; Monge, M. Ángeles; Ruiz-Valero, Caridad; Snejko, Natalia;

doi: 10.1021/cm051362e

handle: 10261/183329

Metal−Organic Scandium Framework: Useful Material for Hydrogen Storage and Catalysis

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Abstract

The 3D polymeric terephthalate of scandium has been synthesized and its structure solved by single-crystal XRD. It was obtained as a single phase and characterized and tested as a hydrogen and nitrogen adsorbent and heterogeneous catalyst as a redox agent in the oxidation of sulfides. The compound shows a BET area of 721 m2 g-1 with a high CBET = 7000. The high chemical and thermal stability and excellent hydrogen sorption properties make this compound a useful material for hydrogen storage.

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