A solid-phase version of the Nozaki–Hiyama allylation of aldehydes with supported allylic bromides

descriptionPublicationkeyboard_double_arrow_right Article 01 Feb 2004 English Publisher:Elsevier BVJournal:Tetrahedron Letters, volume 45, pages 1,511-1,513 (issn: 0040-4039,

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Authors: Breitenstein, Klaus; Llebaria, Amadeu; Delgado Cirilo, Antonio;

doi: 10.1016/j.tetlet.2003.12.017

handle: 10261/18192

A solid-phase version of the Nozaki–Hiyama allylation of aldehydes with supported allylic bromides

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Abstract

A solid-phase version of the Nozaki–Hiyama allylation of supported allylic bromides with aldehydes is described. α-Methylene γ-butyrolactones 7 can be obtained by cyclization cleavage of the supported intermediate homoallylic alcohols 6.

Financial support from the European Union (contract FMRXCT98-0235), and DURSI Generalitat de Catalunya (2001SGR00342 and 2001SGR00085).

3 pages, 3 schemes, 1 table.-- Available on line Dec 23, 2003.

Peer reviewed

Related Organizations

University of Barcelona
Spain

Keywords

Chromium, Lactones, Allylation, Solid phase

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