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Phosphorylation Catalyzed by Dihydroxyacetone Kinase

descriptionPublicationkeyboard_double_arrow_right Article 08 May 2018 Spain English Publisher:WileyJournal:European Journal of Organic Chemistry, volume 2,018, pages 2,892-2,895 (issn: 1434-193X, eissn: 1099-0690, Copyright policy )
Authors: Dominik Gauss; Israel Sánchez‐Moreno; Isabel Oroz‐Guinea; Eduardo García‐Junceda; Roland Wohlgemuth;

doi: 10.1002/ejoc.201800350

handle: 10261/179399

Phosphorylation Catalyzed by Dihydroxyacetone Kinase

Abstract

Site‐ and enantioselective kinases have been very useful catalysts for biocatalytic phosphorylations in straightforward syntheses of phosphorylated metabolites. Biocatalytic phosphorylations catalyzed by recombinant dihydroxyacetone kinase beyond the dihydroxyacetone substrate have been investigated with quantitative 31P NMR spectroscopy using pyruvate‐kinase‐catalyzed ATP regeneration. A nearly 100 % conversion of d‐glyceraldehyde to d‐glyceraldehyde 3‐phosphate has been found. Interestingly, with pure l‐glyceraldehyde as substrate, practically no formation of l‐glyceraldehyde 3‐phosphate was observed.

Country
Spain
Related Organizations
Keywords

Biocatalysis, Enzyme catalysis, Kinases, Phosphorylation, Homogeneous catalysis

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
OpenAIRE UsageCountsViews provided by UsageCounts
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16
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40
135
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