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Recolector de Ciencia Abierta, RECOLECTA
Conference object . 2013 . Peer-reviewed
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Recolector de Ciencia Abierta, RECOLECTA
Conference object . 2019 . Peer-reviewed
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Preparación de Aminoácidos con Alta Pureza Óptica

descriptionPublicationkeyboard_double_arrow_right Conference object 01 Jan 2013
Authors: Romero Estudillo, Iván Omar; Boto, Alicia;

handle: 10261/179208

Preparación de Aminoácidos con Alta Pureza Óptica

Abstract

La obtención de aminoácidos no naturales ópticamente puros que luego puedan ser introducidos en péptidos bioactivos o catalíticos para modular su conformación y actividad es un área de gran interés en síntesis orgánica y química médica.1,2En esta comunicación se describe el uso de aminoácidos naturales, comerciales y baratos para obtener bibliotecas de aminoácidos no naturales de alta pureza óptica y de alto valor añadido. Esta conversión tiene como paso clave un proceso dominó de escisión radicalaria-oxidación,3 llevado a cabo con reactivos de yodo hipervalente y yodo, bajo irradiación con luz visible. También se explora el uso de microondas para activar la reacción, en sustitución de la luz visible.

Este trabajo fue financiado por el Plan Nacional de I+D (Proyecto CTQ2009-07109), del Ministerio de Ciencia e Innovación/ Economía y Competitividad, y los Fondos Europeos de Desarrollo Regional (FEDER). I.R.E. agradece al CSIC su contrato JAE predoctoral.

Trabajo presentado en la XVII Semana Científica "Antonio González" celebrada en San Cristóbal de La Laguna (Tenerife) del 7 al 11 de octubre de 2013.

Peer Reviewed

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    popularity
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    influence
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
Green