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Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

descriptionPublicationkeyboard_double_arrow_right Article 30 Jan 2019 Spain English Publisher:American Chemical Society (ACS)Journal:Inorganic Chemistry, volume 58, pages 2,265-2,269 (issn: 0020-1669, eissn: 1520-510X, Copyright policy )
Authors: Miguel A. Esteruelas; Israel Fernández; Cristina García-Yebra; Jaime Martín; Enrique Oñate;

doi: 10.1021/acs.inorgchem.8b03366

pmid: 30698418

handle: 10261/176297

Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity

Abstract

The discovery of cycloosmathioborane compounds is reported. These species, which are prepared by the simultaneous dehydrogenation of a trihydride hydrogensulfide osmium(IV) complex and a BH3NHR2 amine-borane, bear an Os-S-B three-membered ring, being a manifestation of the 4 n + 2 Hückel aromaticity in which n = 0 and where the two π electrons of the ring are provided by the S atom.

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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