Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1980 English Publisher:Royal Society of Chemistry (RSC)Journal:J. Chem. Soc., Chem. Commun. (issn: 0022-4936,

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Authors: Hernández, Rosendo; Rivera, Augusto; Salazar, José A.; Suárez, Ernesto;

doi: 10.1039/c39800000958

handle: 10261/17572

Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms

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Abstract

Photolysis of N-iodonitroamines generated in situ from the steroidal nitroamines 6β-nitroamino-5α-cholestan-3β-ol acetate, 6β-nitroamino-5α-cholestane-3β,5α-diol diacetate, and 20R-nitroaminopregn-5-en-3-ol acetate removes hydrogen atoms from the Me-18 and Me-19 groups to give 6β-,19-N-nitroepinino-5α-cholestan-3β-ol acetate, 6β,19-N-nitroepinino-5α-cholestane-3β5α-diol diacetate, and 18,20R-N-nitroepiminopregn-5-en-3β-ol acetate.

A.R. thanks the Centro Iberoamericano de Cooperación of Spain for a fellowship.

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