One-pot synthesis of aryl glycines and other unnatural amino acids from serine derivatives

descriptionPublicationkeyboard_double_arrow_right Article 01 Nov 2002 English Publisher:Elsevier BVJournal:Tetrahedron Letters, volume 43, pages 8,269-8,272 (issn: 0040-4039,

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Authors: Boto, Alicia; Hernández, Rosendo; Montoya, Adriana; Suárez, Ernesto;

doi: 10.1016/s0040-4039(02)02023-3

handle: 10261/16753

One-pot synthesis of aryl glycines and other unnatural amino acids from serine derivatives

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Abstract

This work was supported by the Investigation Programm PPQ2000-0728 of the Plan Nacional de Investigación Científica, Desarrollo e Innovación Tecnológica, Dirección General de Investigación, Ministerio de Ciencia y Tecnología, Spain.

A mild and highly efficient one-pot synthesis of aryl glycines from easily available serine derivatives is described. This methodology is also applied to the synthesis of other uncommon amino acids.

4 pages, 1 table, 4 schemes.-- Printed version published Nov 11, 2002.

Related Organizations

Spanish National Research Council
Spain

Keywords

N-acyliminium ions, Fragmentation, Aryl glycines, Unnatural amino acids, Nucleophilic addition, Alkoxyl radicals

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