Intramolecular 1,8-Hydrogen Abstraction Between Glucopyranose Units in a Disaccharide Model Promoted by Alkoxy Radicals

descriptionPublicationkeyboard_double_arrow_right Article 01 Mar 2002 German Publisher:WileyJournal:Angewandte Chemie, volume 114, pages 884-886 (issn: 0044-8249, eissn: 1521-3757,

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Authors: Francisco, C.G.; Herrera, A.J.; Kennedy, A.R.; Melian, D.; Suarez, E.;

doi: 10.1002/1521-3757(20020301)114:5<884::aid-ange884>3.0.co;2-s , 10.1002/1521-3773(20020301)41:5<856::aid-anie856>3.0.co;2-f

pmid: 12491359

handle: 10261/16750

Intramolecular 1,8-Hydrogen Abstraction Between Glucopyranose Units in a Disaccharide Model Promoted by Alkoxy Radicals

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Abstract

The use of radical reactions in carbohydrate chemistry has recently attracted considerable attention in the synthetic community. Among free radical reactions intramolecular hydrogen abstraction (IHA) has been comparatively less studied in these systems.

This work was supported by the Investigation Program no. PB96-1461 of the Dirección General de Investigación Científica y Técnica, Spain. A.J.H. thanks the Ministerio de Educación y Ciencia, Spain, for a fellowship.

3 pages, 3 schemes.-- PMID: 12491359 [PubMed].-- Supporting information available at: http://www.wiley-vch.de/contents/jc_2002/2002/z18262_s.pdf

Related Organizations

University of Strathclyde
United Kingdom
Spanish National Research Council
Spain
University of La Laguna
Spain

Keywords

Radical reactions, Heparin, Carbohydrates, 540, Disaccharides, Chemistry, Glucose, Alcohols, Conformation analysis, Glycosides, Hydrogen transfer, Oxidation-Reduction

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