Intramolecular hydrogen abstraction. The use of organoselenium reagents for the generation of alkoxy radicals

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1988 English Publisher:Elsevier BVJournal:Tetrahedron Letters, volume 29, pages 5,429-5,432 (issn: 0040-4039,

Copyright policy )

Authors: Dorta, Rosa L.; Francisco, Cosme G.; Freire, Raimundo; Suárez, Ernesto;

doi: 10.1016/s0040-4039(00)82887-7

handle: 10261/16413

Intramolecular hydrogen abstraction. The use of organoselenium reagents for the generation of alkoxy radicals

- Summary
- Metrics

Abstract

The alkoxy radical intermediates, produced by photolysis of several hydroxy compounds in the presence of diphenylselenuranes (1) and iodine, undergo intramolecular hydrogen abstraction to afford cyclic ethers in good yield.

This work was supported by the Investigation Programme of the Comisión Asesora de Investigación Científica y Técnica.

4 pages, 1 table, 1 scheme.

Impact byBIP!

	selected citations These citations are derived from selected sources. This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	37
	popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.	Top 10%
	influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).	Top 10%
	impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.	Average