On the formation of gold nanoparticles from [AuIIICl4]− and a non-classical reduced polyoxomolybdate as an electron source: a quantum mechanical modelling and experimental study

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2016 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:New Journal of Chemistry, volume 40, pages 1,029-1,038 (issn: 1144-0546, eissn: 1369-9261,

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Authors: Lang, Z.; Maicas Gabas, I.; López, X.; Clotet, A.; Martínez de la Fuente, J.; Mitchell, S.G.; Poblet, J.M.;

doi: 10.1039/c5nj02773j

handle: 10261/148136

On the formation of gold nanoparticles from [AuIIICl4]− and a non-classical reduced polyoxomolybdate as an electron source: a quantum mechanical modelling and experimental study

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Abstract

DFT calculations and experimental data prove that the [Na{(MoV2O4)3(μ2-O)3(μ2-SO3)3(μ6-SO3)}2]15− POM is capable of completely reducing Au(iii) to Au(0).

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