A First Cyclodextrin-Transition Metal Coordination Polymer

descriptionPublicationkeyboard_double_arrow_right Article 22 Sep 2016 Spain English Publisher:American Chemical Society (ACS)Journal:Crystal Growth & Design, volume 16, pages 5,598-5,602 (issn: 1528-7483, eissn: 1528-7505,

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Authors: Xu, Heng; Rodríguez-Hermida, Sabina; Pérez-Carvajal, Javier; Juanhuix, Judith; Imaz, Inhar; Maspoch Comamala, Daniel;

doi: 10.1021/acs.cgd.6b01115

handle: 10261/143194

A First Cyclodextrin-Transition Metal Coordination Polymer

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Abstract

The synthesis, X-ray crystallographic structure, and water uptake measurements of the first coordination polymer made of a cyclodextrin and a transition metal ion (in this case, Cu) are shown. This coordination polymer is made by connecting paddle-wheel Cu units through a γ-cyclodextrin functionalized with eight carboxylate groups, is stable in water, and shows selective water-induced reversible structural transformations.

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Spain

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Keywords

X-ray crystallographic structures, Carboxylate groups, Water-uptake measurements, Coordination Polymers, Metal-coordination polymer, Functionalized, Gamma-cyclodextrin, Structural transformation

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