A Capped Octahedral MHC6 Compound of a Platinum Group Metal

descriptionPublicationkeyboard_double_arrow_right Article 02 Jun 2016 English Publisher:WileyJournal:Chemistry – A European Journal, volume 22, pages 9,106-9,110 (issn: 0947-6539, eissn: 1521-3765,

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Authors: Eguillor, Beatriz; Esteruelas, Miguel A.; Lezáun, Virginia; Oliván, Montserrat; Oñate, Enrique; Tsai, Jui-Yi; Xia, Chuanjun;

doi: 10.1002/chem.201601729

pmid: 27123555

handle: 10261/134018

A Capped Octahedral MHC6 Compound of a Platinum Group Metal

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Abstract

AbstractA MHC6 complex of a platinum group metal with a capped octahedral arrangement of donor atoms around the metal center has been characterized. This osmium compound OsH{κ2‐C,C‐(PhBIm‐C6H4)}3, which reacts with HBF4 to afford the 14 e− species [Os{κ2‐C,C‐(PhBIm‐C6H4)}(Ph2BIm)2]BF4 stabilized by two agostic interactions, has been obtained by reaction of OsH6(PiPr3)2 with N,N′‐diphenylbenzimidazolium chloride ([Ph2BImH]Cl) in the presence of NEt3. Its formation takes place through the C,C,C‐pincer compound OsH2{κ3‐C,C,C‐(C6H4‐BIm‐C6H4)}(PiPr3)2, the dihydrogen derivative OsCl{κ2‐C,C‐(PhBIm‐C6H4)}(η2‐H2)(PiPr3)2, and the five‐coordinate osmium(II) species OsCl{κ2‐C,C‐(PhBIm‐C6H4)}(PiPr3)2.

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