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Recolector de Ciencia Abierta, RECOLECTA
Article . 2013 . Peer-reviewed
Data sources: Recolector de Ciencia Abierta, RECOLECTA
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Recolector de Ciencia Abierta, RECOLECTA
Article . 2015 . Peer-reviewed
Data sources: Recolector de Ciencia Abierta, RECOLECTA
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DIGITAL.CSIC
Article . 2015 . Peer-reviewed
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Dalton Transactions
Article . 2013 . Peer-reviewed
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Dalton Transactions
Article . 2013
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https://dx.doi.org/10.1039/c2d...
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Mono- and dinuclear osmium N,N′-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2013 Spain English Publisher:Royal Society of Chemistry (RSC)Journal:Dalton Transactions, volume 42, page 3,597 (issn: 1477-9226, eissn: 1477-9234, Copyright policy )
Authors: Esteruelas, Miguel A.; Fernández, Israel; Gómez-Gallego, Mar; Martín-Ortíz, Mamen; Molina, Pedro; Oliván, Montserrat; Otón, Francisco; +2 Authors

doi: 10.1039/c2dt32548a

pmid: 23292252

handle: 10261/111255

Mono- and dinuclear osmium N,N′-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry

Abstract

The efficient synthesis of mono- and dinuclear Os(IV) bipyridyl complexes is reported. These compounds show a two-step oxidation process leading to notable structural changes, which are reflected in their emission properties. During the second oxidation process a tetracation with a hydride-dihydrogen structure (instead of a trihydride) is formed. This results in a significant bathochromic shift of the emission band, accompanied by a moderate increase in intensity.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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