PHASE RELATIONS IN THE PSEUDO-TERNARY SYSTEM Li3VO4-Li4SiO4-Li4GeO4

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1983Publisher:Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of SciencesJournal:Acta Physica Sinica, volume 32, page 1,061 (issn: 1000-3290, eissn: 1000-3290,

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Authors: null CHE GUANG-CAN; null TANG DI-SHENG;

doi: 10.7498/aps.32.1061

PHASE RELATIONS IN THE PSEUDO-TERNARY SYSTEM Li3VO4-Li4SiO4-Li4GeO4

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Abstract

Phase transitions of Li3VO4, Li4SiO4 and isothermal section of the pseudo-ternary systems Li3VO4-Li4SiO4-Li4GeO4 have been investigated by means of DTA and X-ray diffra-ction techniques. It has been found that the high temperature phase of Li3VO4 can be stabilized to room temperature by addition of Li4SiO4 (or Li4GeO4) in Li3VO4-Li4SiO4 (or Li3VO4-Li4GeO4) binary systems. New Li+-conductors with high Li+-conductivity has been obtained. Experimental results show that stabilization of high temperature phase exhibiting high ionic conductivity could be one of the way for exploring new Li+-conducting materials.

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