The enthalpies of combustion and formation of 2,2'-dichloroethyl sulfide

descriptionPublicationkeyboard_double_arrow_right Article 01 Sep 1975 English Publisher:National Institute of Standards and Technology (NIST)Journal:Journal of Research of the National Bureau of Standards Section A: Physics and Chemistry, volume 79A, page 635 (issn: 0022-4332,

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Authors: Walter H, Johnson;

doi: 10.6028/jres.079a.024

pmid: 32184521

pmc: PMC6565419

The enthalpies of combustion and formation of 2,2'-dichloroethyl sulfide

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Abstract

The enthalpies of combustion and formation of 2,2'-dichlorethyl sulfìde (mustard gas) have been determined by combustion in an adiabatic rotating-bomb calorimeter. The bomb process has been corrected to: C 4 H 8 Cl 2 S ( liq ) + 7 O 2 ( g ) + 98 H 2 O ( liq ) → 4 CO 2 ( g ) + [ 2 HCl + H 2 SO 4 + 100 H 2 O ] ( liq ) for which the following values were obtained: Δ H c ° ( 25 ° C ) = - 3163.49 ± 1.26 kJ / mol and Δ H f ° ( 25 ° C ) = - 200.57 ± 1.58 kJ / mol . .

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