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Removal of basic dyes by biosorption

Authors: Pimol Punjongharn;

Removal of basic dyes by biosorption

Abstract

Green macroalga Caulerpa lentillifera was found to have adsorption capacity for basic dyes, Astrazon Blue FGRL, Astrazon Red GTLN, and Astrazon Golden Yellow GL-E. The initial dye concentration was in the range from 100-1800 mg l[superscript -1] . The dried algal sorbent was ground and sieved into 3 sizes: S (0.1-0.84 mm), M (between 0.84-2.0 mm), and L sizes (larger than 2.0 mm). For all conditions examined in this work (at 25 degree Celsius in batch systems), the adsorption reached equilibrium within the first hour. The kinetic data corresponded well with the pseudo second-order kinetic model where the rate constant, k[subscript 2], decreased as the sorbent size increased for all dyes. The adsorption isotherms followed both Langmuir and Freundlich models. Among three sorbent sizes, S size gave the highest adsorption capacity followed by M and L sizes, respectively. A reduction of sorbent size increased the specific surface area for mass transfer, and also increased the total pore volume, thus providing more active sites for adsorption. The adsorption of AB was adversely influenced by the protonation of algal surface at low pH. On the other hand, the adsorption of AR and AY could be due to weak electrostatic interaction, which was not significantly affected by pH. Increasing salinity of the system caused a decrease in adsorption capacity possibly due to the competition between Na[superscript +] ions and the dye cations for the binding sites on algal surface. Moreover, an increase in salinity generated a compressed electrical double layer on the algal surface which exerted repulsive force, retarding the adsorption of positive charged molecules such as the basic dyes.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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