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https://doi.org/10.5821/disser...
Doctoral thesis . 2023 . Peer-reviewed
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Fractura de compuestos polipropileno-talco

Authors: Velasco Perero, José Ignacio;

Fractura de compuestos polipropileno-talco

Abstract

La investigación realizada en esta tesis se ha centrado en la caracterización de la fractura de materiales compuestos por una matriz de polipropileno homopolímero isotáctico y diferentes fracciones de partículas laminares de talco. Estos materiales se emplean en la actualidad para la fabricación de piezas por inyección, especialmente en el sector de automoción. Por extrusión de doble tornillo se prepararon dos series de materiales conteniendo diferentes fracciones de talco disperso, el cual fue previamente tratado con agentes de acoplamiento de tipo silano organofuncional para inducir adhesión en la interfase. Se preparó una serie equivalente con talco sin tratar con fines comparativos. Las probetas para los ensayos se obtuvieron mediante moldeo por inyección. Además de caracterizar térmica y mecánicamente dichos materiales, se ha estudiado la influencia del porcentaje de partículas, del grado de adhesión en la interfase, y de la velocidad de solicitación, sobre los valores de la tenacidad y energía de fractura, y se han identificado los micromecanismos responsables de su deformación y fractura. Los resultados obtenidos se discuten asimismo sobre la base de las características morfológicas y microestructurales observadas. The investigation was focused on the characterization of the fracture of plastic materials made up of isotactic polypropylene (homopolymer) containing different fractions of lamellar talc particles. Because of their rigidity and low cost, these materials are used at the present time for the manufacture of injection-molding parts, especially for the automobile sector. Different fractions of talc were dispersed into the polypropylene matrix by using a co-rotating twin-screw extruder. Two series of composites were prepared with different fractions of both untreated and silane-treated talc. The surface treatment of the talc with organofunctional silane was previously performed in order to promote better interfacial adhesion in the composite. Standard (ASTM) test specimens were prepared by injection-molding. The composites were characterized thermally and mechanically. The influence of the talc percentage, the adhesion degree at the interface and the loading rate on the fracture toughness values was also studied. The micromechanisms responsible for the material deformation and crack propagation could also be identified. The obtained results are discussed on a basis of the morphological and microstructure characteristics.

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Spain
Keywords

propiedades mecánicas, Àrees temàtiques de la UPC::Enginyeria dels materials, Materials compostos, integral-J, :Enginyeria dels materials [Àrees temàtiques de la UPC], polipropileno, propiedades térmicas, extrusión, 620, materiales compuestos, cristalización, plásticos, polímeros, impacto, fractura, inyección, talco

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selected citations
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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