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Cellulose Microfibril Angle in Wood and Its Dynamic Mechanical Significance

زاوية اللييفات الدقيقة السليلوزية في الخشب وأهميتها الميكانيكية الديناميكية
Authors: Aykut Tamer; Fakhreza Abdul;

Cellulose Microfibril Angle in Wood and Its Dynamic Mechanical Significance

Abstract

L'orientation des microfibrilles de cellulose dans les couches S2 des parois cellulaires du bois tendre a une influence significative sur les propriétés mécaniques du bois. L'angle entre les fibrilles de cellulose et l'axe longitudinal des cellules, l'angle des microfibrilles, l'AMF se sont révélés être un facteur critique dans la détermination des propriétés physiques et mécaniques du bois (Cave, 1997). Pour cette raison, des efforts considérables ont été consacrés à la mesure de l'AMF de la cellulose. La mesure directe de l'AMF a été effectuée en mettant en évidence des microfibrilles dans les parois cellulaires individuelles avec une coloration à l'iode, mais les techniques les plus largement adoptées utilisent soit la diffraction des rayons X grand angle, soit la diffusion des rayons X petit angle. Les travaux pionniers de Cave (1966) et Meylan (1967) ont conduit à l'utilisation du paramètre « T » dérivé de la distribution de la courbe de l'intensité diffractée par les plans (002) des fibrilles de cellulose.

La orientación de las microfibrillas de celulosa en las capas S2 de las paredes celulares de la madera blanda tiene una influencia significativa en las propiedades mecánicas de la madera. El ángulo entre las fibrillas de celulosa y el eje celular longitudinal, el ángulo de las microfibrillas, MFA se encontró que era un factor crítico en la determinación de las propiedades físicas y mecánicas de la madera (Cave, 1997). Por esta razón, se ha dirigido un esfuerzo considerable hacia la medición del MFA de celulosa. La medición directa de MFA se ha realizado destacando las microfibrillas en las paredes celulares individuales con tinción de yodo, pero las técnicas más ampliamente adoptadas utilizan difracción de rayos X de gran angular o dispersión de rayos X de pequeño ángulo. El trabajo pionero de Cave (1966) y Meylan (1967) condujo al uso del parámetro 'T' derivado de la distribución de la curva de la intensidad difractada por los planos (002) de las fibrillas de celulosa.

The orientation of the cellulose microfibrils in the S2 layers of the cell walls of softwood has a significant influence on the mechanical properties of wood. The angle between the cellulose fibrils and the longitudinal cell axis, the microfibril angle, MFA was found to be a critical factor in determining the physical and mechanical properties of wood (Cave, 1997). For this reason, considerable effort has been directed towards the measurement of the cellulose MFA. Direct measurement of MFA has been made by highlighting microfibrils in individual cell walls with iodine staining, but the most widely adopted techniques use either wideangle X-ray diffraction or small-angle X-ray scattering The pioneering work of Cave (1966) and Meylan (1967) led to the use of the 'T' parameter derived from the curve distribution of the intensity diffracted by the (002) planes of the cellulose fibrils.

إن اتجاه اللييفات الدقيقة السليلوزية في طبقات S2 من جدران الخلايا من الخشب اللين له تأثير كبير على الخواص الميكانيكية للخشب. تم العثور على الزاوية بين لييفات السليلوز ومحور الخلية الطولي، وزاوية اللييفات الدقيقة، MFA لتكون عاملاً حاسماً في تحديد الخصائص الفيزيائية والميكانيكية للخشب (Cave، 1997). لهذا السبب، تم توجيه جهد كبير نحو قياس MFA السليلوز. تم إجراء قياس مباشر لـ MFA من خلال تسليط الضوء على اللييفات الدقيقة في جدران الخلايا الفردية مع تلطيخ اليود، ولكن التقنيات الأكثر اعتمادًا على نطاق واسع تستخدم إما حيود الأشعة السينية واسع الزاوية أو تشتت الأشعة السينية صغير الزاوية أدى العمل الرائد لـ Cave (1966) و Meylan (1967) إلى استخدام معلمة "T" المشتقة من توزيع المنحنى للشدة التي تحيدها مستويات (002) من ألياف السليلوز.

Keywords

Composite material, Microfibril, Materials Science, Building and Construction, Nanocellulose: Properties, Production, and Applications, Materials science, Biomaterials, Mechanics and Properties of Paper Materials, Engineering, Chemical engineering, Wood Science and Technology, Mechanics of Materials, Physical Sciences, Mechanical Properties, Cellulose, FOS: Chemical engineering, Polymer science

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
12
Top 10%
Average
Average
hybrid