Ultra-light metal foams became an attractive research field both from the scientific and industrial applications view points. Closed-cell metal foams, in particular aluminium alloy (Al-alloy) ones can be used as lightweight, energy-absorption and damping structures in different industrial sectors, detaining an enormous potential when transportation is concerned. Despite the several manufacturing methods available, ultra-light metal foam applications seem to be restricted to a rather less demanding market in what concerns final product quality. The current available manufacturing processes enable effective control of density through process parameters manipulation. However, none of them allow for appropriate control of the cellular structures during its formation, leading to severe drawbacks in what concerns final product structural and mechanical properties. The latter, is undoubtedly the main reason for the lack of commercial acceptance of these ultra-light metal foams in product quality highly demanding sectors, such as the automotive or aeronautical sectors. The resolution of this problem is the main challenge of the scientific community in this field. To accomplish the latter two approaches may be followed: i) to develop new manufacturing processes or modify the existing ones to obtain foams with more uniform cellular structures. (ii) to understand and quantify the thermo-physicochemical mechanisms involved during the foam formation in order to control the process, avoiding the occurrence of such imperfections and structural defects.