
U radu je predstavljeno istraživanje oslobađanja formaldehida iz uslojenih drvenih ploča proizvedenih od furnira bukve, topole, johe i običnog bora tretiranih s 5 %-tnim vodenim otopinama najčešće upotrebljavanih usporivača gorenja: cinkova borata, borne kiseline, monoamonijeva fosfata i amonijeva sulfata. Za lijepljenje furnira upotrijebljene su dvije vrste urea-formaldehidnog ljepila (UF) različitog omjera slobodnih formaldehida (0,16 i 0,20 %) u njemu. Oslobađanje formaldehida iz uslojenih drvenih ploča određeno je perforatorskom metodom opisanom u standardu EN 717-3. Istraživanja su pokazala da je oslobađanje formaldehida iz uzoraka ploča proizvedenih od furnira bukve, topole, johe i običnog bora i tretiranih cinkovim boratom i bornom kiselinom veće nego iz kontrolnih uzoraka ploča, dok je za ploče tretirane monoamonijevim fosfatom i amonijevim sulfatom ustanovljena manja količina oslobođenog formaldehida. To vrijedi za sve četiri vrste drva. Tretiranje ploča monoamonijevim fosfatom i amonijevim sulfatom rezultirala je znatnim smanjenjem emisije formaldehida iz proizvedenih uslojenih drvenih ploča. Stoga se u nekim područjima uporabe u kojima se ne zahtijeva velika čvrstoća ploča mogu upotrebljavati ploče od uslojenog drva izrađene od furnira tretiranih monoamonijevim fosfatom i amonijevim sulfatom jer se iz njih oslobađaju manje količine formaldehida.
In the present study, it was aimed to investigate the formaldehyde release of plywood panels manufactured from beech, poplar, alder and scots pine veneers treated with 5 % aqueous solutions of commonly used fire retardants: zinc borate, boric acid, monoammonium phosphate and ammonium sulfate. Two types of urea formaldehyde (UF) resin with different free formaldehyde ratios (0.16 % and 0.20 %) in adhesive were used as adhesive. Formaldehyde release of plywood panels was determined according to fl ask method described in EN 717-3 standard. As a result of this study, it was found that formaldehyde release from panels produced by beech, poplar, alder and scots pine veneers treated with zinc borate and boric acid were higher than those of control panels, while lower formaldehyde release was obtained for panels treated with monoammonium phosphate and ammonium sulfate. This is valid for all four wood species. Treatment of monoammonium phosphate and ammonium sulfate caused considerable reduction in formaldehyde emission from manufactured plywood panels. In some usage areas, where high strength properties are not expected, plywood panels manufactured from veneers treated with monoammonium phosphate and ammonium sulfate may be used for reducing formaldehyde release.
urea formaldehyde, formaldehyde release, fire retardant, oslobađanje formaldehida, furnir, urea-formaldehid, plywood, veneer, usporivač gorenja, ploča od uslojenog drva
urea formaldehyde, formaldehyde release, fire retardant, oslobađanje formaldehida, furnir, urea-formaldehid, plywood, veneer, usporivač gorenja, ploča od uslojenog drva
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