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The Chemistry of the Zinc Oxide Cure of Halobutyl

Authors: R. J. Pancirov; I. Kuntz; R. L. Zapp;

The Chemistry of the Zinc Oxide Cure of Halobutyl

Abstract

Abstract The studies described in this papier lead to certain conclusions. The crosslinking reaction of halobutyl with zinc oxide does not give rise to ether crosslinks. All the evidence indicates that the chemistry involves the formation of carbon-carbon bonds by an alkylation type chemistry. The dehydrohalogenation of the halobutyl to form a zinc chloride catalyst is a key feature of the crosslinking chemistry. But conjugated diene butyl and Diels-Alder reactions are not the major reaction pathway for the zinc oxide crosslinking reaction. These conclusions have significance for the zinc oxide cure of CR which has an active allylic halide structure formed by 1,2-monomer enchainment.

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
25
Top 10%
Top 10%
Average
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