Powered by OpenAIRE graph
Found an issue? Give us feedback
addClaim

The Mechanism of Alternating Current Corrosion of API Grade X65 Pipeline Steel

Authors: Iannuzzi, Mariano; Ghanbari, E.; Lillard, R.;

The Mechanism of Alternating Current Corrosion of API Grade X65 Pipeline Steel

Abstract

In the present work, corrosion rates of API grade X65 pipeline steel in sodium chloride solutions with and without alternating currents (AC) at different direct current (DC) potentials were measured using weight loss analysis. The results show that the effect of AC is most pronounced near the open-circuit potential; at more positive potentials, the rates approach those of the ohmic drop/mass transport-limited DC rates. Correspondingly, at negative potentials the rates decrease. Surprisingly, it was found that at all potentials, the AC corrosion rate was equal to the average AC current in the system. The data generated from weight loss experiments were compared with the results from a model for AC corrosion that was developed using a modified Butler-Volmer approach. The model considers the anodic and cathodic Tafel slopes, diffusion limited oxygen transport, interfacial capacitance, and solution resistance. Both experimental and model results showed the importance of the interfacial capacitance on the rate of AC corrosion, especially at a frequency of 60 Hz. The models were also used to explain the observation that the AC corrosion rate was equal to the average AC current in the system.

Country
Australia
Related Organizations
Keywords

620

  • BIP!
    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    34
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 10%
Powered by OpenAIRE graph
Found an issue? Give us feedback
selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
34
Top 10%
Top 10%
Top 10%
Upload OA version
Are you the author of this publication? Upload your Open Access version to Zenodo!
It’s fast and easy, just two clicks!