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Article . 2011 . Peer-reviewed
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https://dx.doi.org/10.48550/ar...
Article . 2011
License: arXiv Non-Exclusive Distribution
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Closed virial equations for hard parallel cubes andsquares

Authors: Woodcock, Leslie V.;

Closed virial equations for hard parallel cubes andsquares

Abstract

A correlation between maxima in virial coefficients (Bn), and "kissing" numbers for hard hyper-spheres up to dimension D=5, indicates a virial equation and close-packing relationship. Known virial coefficients up to B7, both for hard parallel cubes and squares, indicate that the limiting differences Bn-B(n-1) behave similar to spheres and disks, in the respective expansions relative to maximum close packing. In all cases, the increment Bn-B(n-1) will approach a negative constant with similar functional form in each dimension. This observation enables closed-virial equations-of-state for cubes and squares to be obtained. In both the 3D and 2D cases, the virial pressures begin to deviate from MD thermodynamic pressures at densities well-below crystallization. These results consolidate the general conclusion, from previous papers on spheres and disks, that the Mayer cluster expansion cannot represent the thermodynamic fluid phases up to freezing as commonly assumed in statistical theories.

UFJF paper 12 pages 7 figures

Keywords

Statistical Mechanics (cond-mat.stat-mech), FOS: Physical sciences, Mathematical Physics (math-ph), Condensed Matter - Statistical Mechanics, Mathematical Physics

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
1
Average
Average
Average
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