Some solubility studies in the system thorium carbonate-sodium carbonate-sodium bicarbonate-sodium sulphate-water

descriptionPublicationkeyboard_double_arrow_right Report , Other literature type 01 Jan 1958Publisher:Natural Resources Canada/CMSS/Information Management

Authors: J C Ingles; F J Kelly;

doi: 10.4095/306648

Some solubility studies in the system thorium carbonate-sodium carbonate-sodium bicarbonate-sodium sulphate-water

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Abstract

The solubility of the thorium pentacarbonate complex has been determined in aqueous solutions containing about 10% total carbonate (carbonate: ,bicarbonate ratio varied from 7:3 to 3:7) and 0 to 10% sodium sulphate at 25° and at 53°C. The Th02 solubility in all cases is of the order of 15 g/1 at 25°C and 35 g/1 at 53°C. At room temperature, it is slightly decreased as the sodium sulphate concentration is increased. The solid phase in equilibrium with these solutions is Na 6 Th(CO 3 ) 5 X H 2 0.

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