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Boletín de la Sociedad Española de Cerámica y Vidrio
Article . 2002 . Peer-reviewed
License: Elsevier TDM
Data sources: Crossref
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Reactividad y propiedades mecánicas de escoria de alto horno activada por álcalis

Reactivity and mechanical properties of alkali activated blast furnace slag
Authors: Escalante-García, J. I.; Méndez-Nonell, J.; Gorokhovsky, A.; Fraire-Luna, P. E.; Mancha-Molinar, H.; Mendoza-Suárez, G.;

Reactividad y propiedades mecánicas de escoria de alto horno activada por álcalis

Abstract

Investigations were carried out to characterize the reactivity and mechanical properties in blast furnace slag pastes activated by 5 alkali systems such as NaOH, waterglass and combinations of Na2CO3, Na2SO4 y Ca(OH)2 in concentrations of 5%. Cubes of 5cm were prepared and cured under water for up to 120 days at 20 and 60°C. The highest compressive strengths were noted for the waterglass activation, followed by one of the combination of 3 compounds, while NaOH activation resulted in the lowest strengths. Increased temperatures favored the strength for the waterglass activation, outperforming those of the Portland cement paste used as control at all times, whereas it had a negative effect for all other activations. The reactivity of the systems, as obtained by measurements of non evaporable water and selective chemical dissolution, indicated that the slag is more reactive under the NaOH activation. Scanning electron microscopy by means of backscattered electrons confirmed the different reactivities and the mechanical properties observed.<br><br>Se realizaron estudios de caracterización de reactividad y propiedades mecánicas en pastas de escoria de alto horno activada por 5 sistemas alcalinos como NaOH, vidrio soluble y combinaciones de Na2CO3, Na2SO4 y Ca(OH)2 en concentraciones de 5%. Se prepararon cubos de 5cm por lado y se curaron durante 120 días a 20 y 60°C bajo agua. Los valores mas altos de resistencia mecánica fueron registrados por el sistema de escoria activada con vidrio soluble, seguido por una de las combinaciones de 3 reactivos químicos, mientras que el desarrollo de propiedades mecánicas fue más pobre con la activación por NaOH. El aumento en la temperatura de curado favoreció la resistencia a la compresión de escoria con vidrio soluble, superando a la del cemento Portland a todos los tiempos de curado; para los otros sistemas el incremento de la temperatura de curado resultó perjudicial. En contraste con las observaciones de resistencia mecánica, la reactividad observada por mediciones de agua no evaporable y disolución química selectiva indicaron que la escoria es mas reactiva en presencia de NaOH. Las imágenes por Microscopía electrónica de barrido utilizando electrones retrodispersados confirmaron las diferentes reactividades y las propiedades mecánicas observadas.

Keywords

Escoria, Clay industries. Ceramics. Glass, productos de hidratación, reactivity, TP785-869, activación alcalina, Blast furnace slag, alkali activation, microstructures, hydration products, reactividad, microestructuras

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
12
Top 10%
Top 10%
Average
gold