The Thre-Component Condensation of Monoterpenes with Formaldehyde and Cyclohexane-1,3-dione. A Simple Route to Polyketide Terpenes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1994 English Publisher:CLOCKSS ArchiveJournal:HETEROCYCLES, volume 37, page 661 (issn: 0385-5414,

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Authors: H. M. R. Hoffmann; Stefan Koser;

doi: 10.3987/com-93-s13

The Thre-Component Condensation of Monoterpenes with Formaldehyde and Cyclohexane-1,3-dione. A Simple Route to Polyketide Terpenes

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Abstract

The framework of polyketide terpenes was obtained by the title tandem reaction which was carried out in one-pot under optimized conditions. Even tetrasubstituted olefins react, sterically hindered octahydro- naphthalene (6) giving tetracyclic propellane (7)

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