Regioselective Allylation to a Tetrahydroisoquinoline

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1992 English Publisher:CLOCKSS ArchiveJournal:HETEROCYCLES, volume 33, page 39 (issn: 0385-5414,

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Authors: Osamu Hoshino; Hiroshi Hara; Akiko Seto;

doi: 10.3987/com-91-s8

Regioselective Allylation to a Tetrahydroisoquinoline

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Abstract

The p-quinol acetate (1a) reacted with allyltrimethylsilane in dichloromethane in the presence of acid (BF 3 .Et 2 O or CF 3 COOH) to give 8-allylcorypalline (3), while in acetonitrile to give 4-allylcorypalline (7), regioselectively. Plausible pathway on formation of 3 and 7 is described

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Tokyo University of Science
Japan

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