Stereoselective Epoxydation of 1-Iridene Derivatives. Total Syntheses of Methyl Chokolate A and Matatabiether

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1990 English Publisher:CLOCKSS ArchiveJournal:HETEROCYCLES, volume 30, page 341 (issn: 0385-5414,

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Authors: Nobuo Kato; Hitoshi Takeshita; Masashi Kamitamari; Shoji Naganuma; Hiroaki Arita;

doi: 10.3987/com-89-s63

Stereoselective Epoxydation of 1-Iridene Derivatives. Total Syntheses of Methyl Chokolate A and Matatabiether

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Abstract

Sharpless oxidation of 1-iridenes stereoselectively afforded trans-epoxy derivatives. As expected, the selectivity was inversed to give cis-epoxy derivatives when 1-iriden-9-ols were similarly treated. The trans- and cis-epoxy derivatives, thus obtained, were converted into optically active methyl chokolate A and matatabiether, respectively

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Kyushu University
Japan

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