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Zayedene: Carbon sp chains in diamond nanocavities

Authors: Francesco Delodovici; Daniel S Choi; Mohamed Al Fahim; Larry A Burchfield; Nicola Manini;

Zayedene: Carbon sp chains in diamond nanocavities

Abstract

We propose a new class of carbon allotropes obtained by combining linear sp carbon chains with sp3 bulk carbon.The structure of these crystalline carbon allotropes consists of sp chains inserted in cylindrical cavities periodically arranged in hexagonal diamond (lonsdaleite).We carry out a detailed computational analysis of the structural, electronic, and vibrational properties of a simple form in this class: a single C6 strand embedded in a nm-sized cavity.We obtain a metallic allotrope exhibiting characteristic high-frequency vibrations associated with the sp chains stretching modes, and characterized by long-time room-temperature stability.In addition, we suggest how numerous similar allotropes could be constructed within this class, that we call zayedene, all characterized by comparable metallicity and high-frequency vibrations.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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