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Beilstein Journal of Organic Chemistry
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Beilstein Journal of Organic Chemistry
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https://dx.doi.org/10.60692/hk...
Other literature type . 2013
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Other literature type . 2013
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https://dx.doi.org/10.3762/bjo...
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Claim

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent

معالجة ثلاثي فلورو الميثيل المحفز بالنحاس للألكينات باستخدام كاشف ثلاثي فلورو الميثيل محفز بالكهرباء
descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 25 Nov 2013 English Publisher:Beilstein InstitutJournal:Beilstein Journal of Organic Chemistry, volume 9, pages 2,635-2,640 (eissn: 1860-5397, Copyright policy )
Authors: Xiaoping Wang; Jin‐Hong Lin; Cheng‐Pan Zhang; Ji‐Chang Xiao; Xiaohui Zheng;

doi: 10.3762/bjoc.9.299 , 10.60692/hkh6g-gbd23 , 10.60692/n6e9j-j3506

pmid: 24367428

pmc: PMC3869243

Copper-catalyzed trifluoromethylation of alkenes with an electrophilic trifluoromethylating reagent

Abstract

An efficient method for the copper-catalyzed trifluoromethylation of terminal alkenes with an electrophilic trifluoromethylating reagent has been developed. The reactions proceeded smoothly to give trifluoromethylated alkenes in good to excellent yields. The results provided a versatile approach for the construction of Cvinyl–CF3 bonds without using prefunctionalized substrates.

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Keywords

Pharmacology, Toxicology and Pharmaceutics, Letter, Science, trifluoromethylation, Pharmaceutical Science, Organic chemistry, Combinatorial chemistry, Catalysis, Trifluoromethyl, Inorganic Chemistry, QD241-441, FOS: Chemical sciences, Reagent, electrophilic trifluoromethylating reagent, Role of Fluorine in Medicinal Chemistry and Pharmaceuticals, Alkyl, Trifluoromethylation, alkenes, catalysis, Q, Life Sciences, Chemistry, Electrophile, copper, Physical Sciences, Chemistry of Noble Gas Compounds and Interactions, Copper

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    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 52
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Top 10%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 Top 10%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
52
Top 10%
Top 10%
Top 10%
Green
Published in a Diamond OA journal