Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene
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Frederick J. Seidl; Noah Z. Burns;
Selective bromochlorination of a homoallylic alcohol for the total synthesis of (−)-anverene
The scope of a recently reported method for the catalytic enantioselective bromochlorination of allylic alcohols is expanded to include a specific homoallylic alcohol. Critical factors for optimization of this reaction are highlighted. The utility of the product bromochloride is demonstrated by the first total synthesis of an antibacterial polyhalogenated monoterpene, (−)-anverene.
- Stanford University United States
- STANFORD UNIVERSITY
- Department of Chemistry Standford University United States
enantioselective catalysis, QD241-441, halogenation, natural products, Science, Q, Organic chemistry, total synthesis, Full Research Paper
enantioselective catalysis, QD241-441, halogenation, natural products, Science, Q, Organic chemistry, total synthesis, Full Research Paper
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These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
Citations provided by BIP!popularityPopularity provided by BIP!
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
Popularity provided by BIP! 18
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