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https://dx.doi.org/10.3762/bjo...
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Relay cross metathesis reactions of vinylphosphonates

descriptionPublicationkeyboard_double_arrow_right Article 19 Aug 2014 English Publisher:Beilstein InstitutJournal:Beilstein Journal of Organic Chemistry, volume 10, pages 1,933-1,941 (eissn: 1860-5397, Copyright policy )
Authors: Raj K. Malla; Jeremy N. Ridenour; Christopher D. Spilling;

doi: 10.3762/bjoc.10.201

pmid: 25246952

pmc: PMC4168886

Relay cross metathesis reactions of vinylphosphonates

Abstract

Dimethyl (β-substituted) vinylphosphonates do not readily undergo cross metathesis reactions with Grubbs catalyst and terminal alkenes. However, the corresponding mono- or diallyl vinylphosphonate esters undergo facile cross metathesis reactions. The improved reactivity is attributed to a relay step in the cross metathesis reaction mechanism.

Related Organizations
Keywords

QD241-441, vinyl phosphonate, Science, Q, Organic chemistry, metathesis, relay, organo phosphorus, Full Research Paper, centrolobine

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    selected citations
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    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    		 8
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    		 Average
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
8
Average
Average
Top 10%
Green
Published in a Diamond OA journal