Simple reaction time was measured to spectral lights matched photometrically in luminance. When these lights were presented on a dimmer achromatic background, reaction time did not vary as a function of wavelength. Moreover, reaction times to white and chromatic lights were the same. When the luminance of the background was the same as that of the chromatic lights, reaction time increased and showed a strong effect of wavelength. Reaction time in this condition appeared to follow a saturation function. The results are described in terms of the operation of achromatic and chromatic processing channels.