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Cross-Coupling Reaction with Lithium Methyltriolborate

descriptionPublicationkeyboard_double_arrow_right Article , Other literature type 28 Dec 2012 Japan English Publisher:MDPI AGJournal:Molecules, volume 18, pages 430-439 (eissn: 1420-3049, Copyright policy )
Authors: Yamamoto, Yasunori; Ikizakura, Kazuya; Ito, Hajime; Miyaura, Norio;

doi: 10.3390/molecules18010430

pmid: 23275051

pmc: PMC6270471

handle: 2115/52062

Cross-Coupling Reaction with Lithium Methyltriolborate

Abstract

We newly developed lithium methyltriolborate as an air-stable white solid that is convenient to handle. The good performance of this triolborate for metal-catalyzed bond-forming reactions was demonstrated in palladium-catalyzed cross-coupling reactions with haloarenes. Cross-coupling reaction of [MeB(OCH2)3CCH3]Li with aryl halides occurred in the presence of Pd(OAc)2/RuPhos complex in refluxing MeOH/H2O and the absence of bases.

Country
Japan
Related Organizations
Keywords

Magnetic Resonance Spectroscopy, Organic chemistry, palladium catalyst, Lithium, 431, Methylation, cross-coupling reaction; palladium catalyst; methyltrioolborate, Article, Catalysis, QD241-441, methyltrioolborate, cross-coupling reaction, Palladium

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citations
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
10
Average
Average
Average
Green
gold
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