The condition for the formation of droplet groups in liquid sprays is poorly understood. This study looks at a simplified model system consisting of two iso-propanol droplets of equal diameter, Dd0, in tandem, separated initially by a center-to-center distance, a20, and moving in the direction of gravity with an initial velocity, Vd0>Vt, where Vt is the terminal velocity of an isolated droplet from Stokes flow analysis. A theoretical analysis based on Stokes flow around this double-droplet system is presented, including an inertial correction factor in terms of drag coefficient to account for large Reynolds numbers (≫1). From this analysis, it is observed that the drag force experienced by the leading droplet is higher than that experienced by the trailing droplet. The temporal evolutions of the velocity, Vd(t), of the droplets, as well as their separation distance, a2(t), are presented, and the time to at which the droplets come in contact with each other and their approach velocity at this time, ΔVd0, are calculated. The effects of the droplet diameter, Dd0, the initial droplet velocity, Vd0, and the initial separation, a20 on to and ΔVd0 are reported. The agreement between the theoretical predictions and experimental data in the literature is good.