Existing databases supporting Online Transaction Processing (OLTP) workloads based on non-volatile memory (NVM) almost all use Multi-Version Concurrency Control (MVCC) protocol to ensure data consistency. MVCC allows multiple transactions to execute concurrently without lock conflicts, reducing the wait time between read and write operations, and thereby significantly increasing the throughput of NVM OLTP engines. However, it requires garbage collection (GC) to clean up the obsolete tuple versions to prevent storage overflow, which consumes additional system resources. Furthermore, existing GC approaches in NVM OLTP engines are inefficient because they are based on methods designed for dynamic random access memory (DRAM) OLTP engines, without considering the significant differences in read/write bandwidth and cache line size between NVM and DRAM. These approaches either involve excessive random NVM access (traversing tuple versions) or lead to too many additional NVM write operations, both of which degrade the performance and durability of NVM. In this paper, we propose TB-Collect, a high-performance GC approach specifically designed for NVM OLTP engines. On the one hand, TB-Collect separates tuple headers and contents, storing data in an append-only manner, which greatly reduces NVM writes. On the other hand, TB-Collect performs GC at the block level, eliminating the need to traverse tuple versions and improving the utilization of reclaimed space. We have implemented TB-Collect on DBx1000 and MySQL. Experimental results show that TB-Collect achieves 1.15 to 1.58 times the throughput of existing methods when running TPCC and YCSB workloads.