We propose a wavelet collocation method for solving the fractional Riccati equation, using the Müntz–Legendre wavelet basis and its associated operational matrix of fractional integration. The fractional Riccati equation is first transformed into a Volterra integral equation with a weakly singular kernel. By employing the collocation method along with the operational matrix, we reduce the problem to a system of nonlinear algebraic equations, which is then solved using Newton–Raphson’s iterative procedure. The error estimate of the proposed method is analyzed, and numerical simulations are conducted to demonstrate its accuracy and efficiency. The obtained results are compared with existing approaches from the literature, highlighting the advantages of our method in terms of accuracy and computational performance.