When dealing with the haziness that is intrinsic in decision analysis-driven decision making procedures, interval-valued intuitionistic fuzzy sets (IVIFSs) can be quite effective. Our approach to solving the multiple attribute decision making (MADM) difficulties, where all of the evidence provided by the decision-makers is demonstrated as interval-valued intuitionistic fuzzy (IVIF) decision matrices, in which all of the components are distinguished by an IVIF number (IVIFN), is based on Aczel–Alsina operational processes. We begin by introducing novel IVIFN operations including the Aczel–Alsina sum, product, scalar multiplication, and exponential. We may then create IVIF aggregation operators, such as the IVIF Aczel–Alsina weighted geometric operator, the IVIF Aczel–Alsina ordered weighted geometric operator, and the IVIF Aczel–Alsina hybrid geometric operator, among others. We present a MADM approach that relies on the IVIF aggregation operators that have been developed. A case study is used to demonstrate the practical applicability of the strategies proposed in this paper. By contrasting the newly developed technique with existing techniques, the method is capable of demonstrating the advantages of the newly developed approach. A key result of this work is the discovery that some of the current IVIF aggregation operators are subsets of the operators reported in this article.