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Understanding Periodic and Non-periodic Chemistry in Periodic Tables

Authors: Changsu Cao; René E. Vernon; W. H. Eugen Schwarz; W. H. Eugen Schwarz; Jun Li; Jun Li;

Understanding Periodic and Non-periodic Chemistry in Periodic Tables

Abstract

The chemical elements are the “conserved principles” or “kernels” of chemistry that are retained when substances are altered. Comprehensive overviews of the chemistry of the elements and their compounds are needed in chemical science. To this end, a graphical display of the chemical properties of the elements, in the form of a Periodic Table, is the helpful tool. Such tables have been designed with the aim of either classifying real chemical substances or emphasizing formal and aesthetic concepts. Simplified, artistic, or economic tables are relevant to educational and cultural fields, while practicing chemists profit more from “chemical tables of chemical elements.” Such tables should incorporate four aspects:(i)typical valenceelectron configurations of bonded atomsin chemical compounds (instead of the common but chemically atypical ground states of free atoms in physical vacuum);(ii)at least three basic chemical properties (valence number, size, and energyof the valence shells), their joint variation across the elements showing principal and secondary periodicity;(iii)elements in which the (sp)8, (d)10, and (f)14valence shells become closed and inert under ambient chemical conditions, thereby determining the “fix-points” of chemical periodicity;(iv)peculiar elements at the top and at the bottomof the Periodic Table. While it is essential that Periodic Tables display important trends in element chemistry we need to keep our eyes open for unexpected chemical behavior in ambient, near ambient, or unusual conditions. The combination of experimental data and theoretical insight supports a more nuanced understanding of complex periodic trends and non-periodic phenomena.

Keywords

Chemistry, periodic tables, chemical elements, electron configurations, orbital radii, QD1-999, chemical properties, orbital energies

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
35
Top 10%
Top 10%
Top 10%
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