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Pure Utrecht University
Doctoral thesis . 2021
License: CC BY ND
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https://doi.org/10.33540/613...
Doctoral thesis . 2021 . Peer-reviewed
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Active Anisotropic Colloids from Colloidal Monolayers

Authors: Napel, Daniël Nathan ten;

Active Anisotropic Colloids from Colloidal Monolayers

Abstract

In this thesis we describe several colloidal model systems. We first study the lattice structures in monolayers of colloidal superballs prepared using the unidirectional rubbing method. In this method, the ordering of the colloidal superballs is achieved by mechanically rubbing them onto a polydimethylsiloxane- (PDMS) coated surface. We show using both small-angle X-ray scattering (SAXS) and scanning electron microscopy (SEM) that a transition in the lattice structures result from a well-defined hexagonal lattice for spherical superballs to the sliding phase for more cube-like superballs. In these lattice structures the cube-like superballs form chains in the direction in which the mechanical rubbing was applied which are able to slide freely with respect to each other. Furthermore, we show that active colloids with an asymmetrically sputter coated metal patch display circling motion under the influence of an alternating electric field. Their velocity and angular velocity can be tuned in situ by varying the magnitude and frequency of the alternating electric field. Finally, we present a method to prepare active anisotropic hydrogel particle. Using this simple and accesible method, particles with an arbitrary geometry and tunable thickness can be prepared which display an active motion under the influence of an alternating electric field.

Country
Netherlands
Related Organizations
Keywords

Superballs, monolayers, colloidal lattices, SAXS, anisotropic colloids, active colloids, active motion, monolayers, Superballs, active motion, anisotropic colloids, active colloids, SAXS, colloidal lattices

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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bronze