Synthesis of gold nano-plates by mercaptide thermolysis in poly(vinyl acetate)
Copyright policy )Synthesis of gold nano-plates by mercaptide thermolysis in poly(vinyl acetate)
Triangular gold nano-plates have been synthesized by thermal decomposition of Au(I) dodecyl-mercaptide (i.e., AuSC12H25) dissolved in poly(vinyl acetate). Such special shape was achieved because of the ability of polymer side-groups (i.e., the acetate groups) to be selectively absorbed on the most acid faces of the growing gold nanocrystals, thus inhibiting crystal development along these crystallographic directions. Nano-plates had an average adge length of ca. 30nm and a thickness of a few nanometers.
Aurora Universities Network, mercaptide, Polymers and Plastics, General Chemical Engineering, Chemical technology, Organic Chemistry, thermolysis, TP1-1185, Materials Chemistry, TA401-492, triangular nano-plates, Physical and Theoretical Chemistry, Materials of engineering and construction. Mechanics of materials, shape control, Nanomaterials
Aurora Universities Network, mercaptide, Polymers and Plastics, General Chemical Engineering, Chemical technology, Organic Chemistry, thermolysis, TP1-1185, Materials Chemistry, TA401-492, triangular nano-plates, Physical and Theoretical Chemistry, Materials of engineering and construction. Mechanics of materials, shape control, Nanomaterials
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