
ABSTRAK: Ion logam chrom VI termasuk limbah logam berat yang perlu dilakukan pengolahan lebih lanjut dengan menggunakan adsorben. Zeolit adalah adsorben yang cocok untuk menyerap ion logam chrom VI karena zeolit merupakan mineral alam yang mempunyai luas permukaan aktif per satuan massa yang besar dan daya afinitas yang cukup kuat. Tujuan dari penelitian ini adalah menentukan model yang cocok untuk kesetimbangan adsorpsi ion logam chrom VI oleh zeolit beserta nilai parameternya, dan mengetahui daya serap zeolit optimal terhadap ion logam chrom VI. Penelitian ini mengunakan metode penerapan model kesetimbangan adsorpsi isoterm yang meliputi 5 persamaan yaitu Adsorpsi Linier (Henry’s Law), Adsorpsi Isoterm Freundlich, Adsorpsi Isoterm Langmuir, Isoterm Brunauer-Emmett-Teller (BET), Persamaan Sigmoidal Chapman. Dari kelima model ini dilakukan fitting data untuk mencari model yang lebih mendekati data. Pencocokan data dilakukan dengan minimasi yang dilakukan oleh program Matlab. Hasil penelitian menunjukkan bahwa model yang cocok yaitu model Adsorpsi Isoterm BET dengan nilai parameter yaitu nilai konstanta adsorpsi isoterm BET (C BET ) sebesar 0,5183 l/mg, kapasitas maksimal adsorben saat setimbang secara teoritis (qs) adalah 149,9977 mg/g dan konsentrasi adsorbat jenuh pada lapisan monolayer (Cs) adalah 184,1691 mg/l. Kata Kunci : Adsorben; Isoterm BET; Model Kesetimbangan Adsorpsi; Zeolit ABSTRACT : Chrom VI metal ion include heavy metal waste which needs further processing using adsorbent. Zeolite is a suitable adsorbent for absorbing strong affinity chrom VI metal ions because zeolite is a natural mineral that has an active surface area per unit of mass and power. The purpose of this study was to determine a suitable model for the equilibrium adsorption of chrom VI metal ion by zeolite along with their parameter values, and to determine the optimal zeolite absorption against chrom VI metal ion. This study uses the method of applying the isotherm adsorption equilibrium model which includes 5 equations namely Linear Adsorption (Henry's Law), Freundlich Isotherm Adsorption, Langmuir Isoterm Adsorption, Brunauer-Emmett-Teller Isotherm (BET), Sigmoidal Chapman Equation. From these five models, data fitting is done to find models that are closer to the data. Data matching is done by minimizing the Matlab program. The results showed that the suitable model is the BET Isotherm Adsorption model with parameter values, namely the BET isotherm adsorption constant value (C BET ) of 0.5183 l/mg, the maximum capacity of the adsorbent at equilibrium theoretical (qs) is 149.9977 mg/g and the saturated adsorbate concentration in the monolayer (Cs) is 184.1691 mg l. Keywords: Adsorbent; BET Isotherm; Adsorption Equilibrium Model; Zeolite
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