
doi: 10.2172/80944
During the past 50 years, a wide variety of chemical compounds have been placed in the 149 single-shell tanks (SSTS) on the Hanford Site. A concern relating to chemical stability, chemical control, and safe storage of the waste is the potential for propagating reactions as a result of ferrocyanide-oxidizer and organic-oxidizer concentrations in the SSTS. Propagating reactions in fuel-nitrate mixtures are precluded if the amounts of fuel and moisture present in the waste are within specified limits. Because most credible ignition sources occur near the waste surface, the main emphasis of this study is toward monitoring and controlling moisture in the top 14 cm (5.5 in.) of waste. The purpose of this engineering study is to recommend a moisture monitoring and control system for use in SSTs containing sludge and saltcake. This study includes recommendations for: (1) monitoring and controlling moisture in SSTs; (2) the fundamental design criteria for a moisture monitoring and control system; and (3) criteria for the deployment of a moisture monitoring and control system in hanford Site SSTs. To support system recommendations, technical bases for selecting and using a moisture monitoring and control system are presented. Key functional requirements and a conceptual design are included to enhance system development and establish design criteria.
Design, Organic Compounds, Radioactive Waste Storage, Hanford Reservation, Sludges, Fluid Injection, Control Systems, Monitors, 05 Nuclear Fuels, Safety Engineering, Radioactive Wastes, Moisture, Ferrocyanides
Design, Organic Compounds, Radioactive Waste Storage, Hanford Reservation, Sludges, Fluid Injection, Control Systems, Monitors, 05 Nuclear Fuels, Safety Engineering, Radioactive Wastes, Moisture, Ferrocyanides
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