
doi: 10.2172/64276
A search is being carried out for new calcium-based S0{sub 2} sorbents for induct injection. More specifically, a search is being carried out for induct injection calcium silicate sorbents that are highly cost effective. The objectives for the current year include the study of sorbents made from Ca(OH){sub 2}, from mixtures of Ca(OH){sub 2} and SiO{sub 2}, and from portland cement. They also include the study of sorbents made from model compounds. During this year, sorbents prepared from Ca(OH){sub 2} and from mixtures of Ca(OH){sub 2} and fumed SiO{sub 2} were investigated. The results show that very good SiO{sub 2}-modified Ca(OH){sub 2} sorbents in which the Si-to-Ca reactant ratio is low can be prepared from Ca(OH){sub 2} and fumed SiO{sub 2}. Sorbents prepared from Ca(OH){sub 2} and natural SiO{sub 2} or natural SiO{sub 2} sources were also studied. The results obtained show that very good SiO{sub 2}-modified Ca(OH){sub 2} sorbents and calcium silicate hydrate sorbents, C-S-H sorbents, can be prepared from Ca(OH){sub 2} and diatomite, pumice or perlite, minerals that are readily available. In addition. sorbents prepared from Ca{sub 3}SiO{sub 5} and {beta}-Ca{sub 2}SiO{sub 4} and from mixtures of these compounds and SiO{sub 2} were studied. The results secured demonstrate that very good C-S-H rich sorbents can be prepared from these compounds and from mixtures of them with SiO{sub 2}. They also provide information useful for interpreting the cement sorbent results. Sorbents prepared from cement and from mixtures of cement and natural SiO{sub 2} or SiO{sub 2} sources were investigated as well. The results secured show that cement and mixtures of it with diatomite, pumice or perlite rapidly yield excellent sorbents with the proper reaction conditions.
20 Fossil-Fueled Power Plants, Calcium Hydroxides, And Peat, Progress Report, Silicates, 40 Chemistry, Silica, Calcium Compounds, 910, Sorbent Injection Processes, 01 Coal, Flue Gas, Adsorbents, Cements, Chemical Preparation, Sulfur Dioxide, Experimental Data, Sorption, Lignite, Desulfurization
20 Fossil-Fueled Power Plants, Calcium Hydroxides, And Peat, Progress Report, Silicates, 40 Chemistry, Silica, Calcium Compounds, 910, Sorbent Injection Processes, 01 Coal, Flue Gas, Adsorbents, Cements, Chemical Preparation, Sulfur Dioxide, Experimental Data, Sorption, Lignite, Desulfurization
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