
doi: 10.2172/5693502
It has been found that while the highly nonuniform direct current breakdown voltages, V/sub s/, of H/sub 2/ and NH/sub 3/ exceed, respectively, those of D/sub 2/ and ND/sub 3/, the V/sub s/ of CH/sub 4/ is substantially lower than that of CD/sub 4/. The former (direct) isotope effect may be attributed to the higher ionization coefficients for the deuterated species compared with the nondeuterated, and the latter (inverse) isotope effect may result from differences in the electron-impact-induced dissociation processes of the isotopic pairs of molecules.
General Physics, Electric Potential, Molecular & Chemical Physics-- Beams & Their Reactions, Odd-Odd Nuclei, Stable Isotopes 640301* -- Atomic, Hydrogen Isotopes, Isotopes, Breakdown, Ammonia, Information, Alkanes, Light Nuclei, Nitrogen Compounds, Hydrogen Compounds, Data, Organic Compounds, Isotope Effects, Hydrides, Elements, Deuterium, Nuclei, Hydrocarbons, Numerical Data, Nonmetals, Deuterium Compounds, Experimental Data, 71 Classical And Quantum Mechanics, Medium Pressure, Methane, Nitrogen Hydrides, Hydrogen
General Physics, Electric Potential, Molecular & Chemical Physics-- Beams & Their Reactions, Odd-Odd Nuclei, Stable Isotopes 640301* -- Atomic, Hydrogen Isotopes, Isotopes, Breakdown, Ammonia, Information, Alkanes, Light Nuclei, Nitrogen Compounds, Hydrogen Compounds, Data, Organic Compounds, Isotope Effects, Hydrides, Elements, Deuterium, Nuclei, Hydrocarbons, Numerical Data, Nonmetals, Deuterium Compounds, Experimental Data, 71 Classical And Quantum Mechanics, Medium Pressure, Methane, Nitrogen Hydrides, Hydrogen
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